كبريتات الالومونيوم (الشبه)

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ALUMINUM SULFATE
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1. Product Identification
Synonyms: Sulfuric acid, aluminum salt (3:2), octadeca hydrate; Cake alum; Patent alum
CAS No.: 10043-01-3 (Anhydrous) 7784-31-8 (Octadecahydrate)
Molecular Weight: 666.44
Chemical Formula: Al2(SO4)3.18H2O
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2. Composition/Information on Ingredients

Ingredient CAS No Percent Hazardous
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Aluminum Sulfate 10043-01-3 98 - 100%

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3. Hazards Identification
Emergency Overview
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WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.

SAF-T-DATA(tm) Ratings (Provided here for your convenience)
Health Rating: 2 - Moderate
Flammability Rating: 0 - None
Reactivity Rating: 1 - Slight
Contact Rating: 2 - Moderate
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: Green (General Storage)

Potential Health Effects
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This material hydrolyzes in water to form sulfuric acid, which is responsible for the irritating effects given below.

Inhalation:
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath.
Ingestion:
Causes irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and diarrhea. There have been two cases of fatal human poisonings from ingestion of 30 grams of alum.
Skin Contact:
Causes irritation to skin. Symptoms include redness, itching, and pain.
Eye Contact:
Causes irritation, redness, and pain.
Chronic Exposure:
No information found.
Aggravation of Pre-existing Conditions:
No information found.
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4. First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention.
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5. Fire Fighting Measures
Fire:
Not considered to be a fire hazard.
Explosion:
Not considered to be an explosion hazard.
Fire Extinguishing Media:
Keep in mind that addition of water can cause the formation of sulfuric acid.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
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6. Accidental Release Measures
Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. Cover spill with sodium bicarbonate or soda ash and mix. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

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7. Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Aluminum sulfate absorbs moisture and becomes a safety hazard when spilled because it absorbs moisture and becomes slippery. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
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8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
15 mg/m3 (TWA) total dust and 5 mg/m3 (TWA)
respirable fraction for Aluminum metal as Al.
-ACGIH Threshold Limit Value (TLV):
1 mg/m3 respirable fraction (TWA), Aluminum metal and Insoluble compounds, A4.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded and engineering controls are not feasible, a half facepiece particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest.. A full-face piece particulate respirator (NIOSH type N100 filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
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9. Physical and Chemical Properties
Appearance:
Colorless crystals.
Odor:
Odorless.
Solubility:
87 g/100 cc water @ 0C (32F).
Specific Gravity:
1.69 @ 17C/4C
pH:
No information found.
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
No information found.
Melting Point:
87C (189F) Decomposes.
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.
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10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Hydrolyzes to form dilute sulfuric acid. Toxic and corrosive oxides of sulfur may be formed when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Corrosive to metals in the presence of water.
Conditions to Avoid:
Moisture and incompatibles.
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12. Ecological Information
Environmental Fate:
No information found.
Environmental Toxicity:
No information found.
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13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
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14. Transport Information
Not regulated.
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16. Other Information
NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0
Label Hazard Warning:
WARNING! HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
Label Precautions:
Avoid breathing dust.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
Avoid contact with eyes, skin and clothing.
Label First Aid:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, wipe off excess material from skin then immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. In all cases, get medical attention.

TECHNOLAB EL-BAHAA GROUP
COLONEL.DR
BAHAA BADR EL-DIN
WATER TREATMENT CONSULTANT
CAIRO-EGYPT
0020117156569
TECHNOLABELBAHAAGP@GMAIL.COM
WWW.TECHNOLABELBAHAAGP.GOOGOOLZ.COM

Aluminium sulphate
Name: Aluminium sulphate for industry
Specification:Al2O3;15.8-17%min; Fe:0.5%max;PH:3.0min;
Water Insolubles: 0.15%max.
Grain size:15mm max(Flakys)
Use: Used in papermaking , printing and dye , tanning leather , fire-fighting equipment , drug and wood preservation ,etc.
Packing:PP/PE 50kg/bag

Aluminium Sulphate kibble
Features Specifications:
Specification: Al2O3:>17%;Fe:<0.005%;PH:>3.0;

Insoluble matter in water:<0.1%, As:<0.0005%; Pb:<0.002%
Granularity: <15mm
Use: treatment of drinking water and industrial water,high grade paper making and high- grade titanium pigment production.

Aluminium sulphate for water treatment
Features Specifications:
Specification: Al2O3: 15.80%min; Fe:0.50%max; PH:3.0min;
Water Insolubles: 0.15%max. As: 0.0005%max; Pb:0.002%max.
Grain size:15mm max (Flakys)
Use: Treatment for the drinking water and water for industrial use.
Packing: PP/PE 50kg/bag

Non-ferric aluminium sulphate
Features Specifications:
Specification: Al2O3:>17%; Fe:<0.005%; PH:>3.0;
Insoluble matter in water:< 0.15%, As:<0.0005%; Pb:<0.002%
Granularity: 15mm<

Powder aluminium sulphate
Features Specifications:
Specification: Al2O3:15.8%,16.5%,17%min; Fe: 0.5%-0.005%max; PH:3.0min;
Water Insolubles: 0.15%max;
Size: :Below 10mesh-100mesh min;
Packing: 50kg/bag PP/PE, 25kg/bag,1 ton bag

Aluminium sulphate for paper making

Quality indexQuality
(Al2O3) %≥ 15.6-17.0
(Fe) %≤0.4-0.5
Water Insolubles %≤0.2
PH (1%water solution) ≥3.0

Lump aluminium sulphate
Quality index Quality
（Al2O3）%≥ 15.8-18.0
（Fe）%≤ 0.003-0.5
Water Insolubles %≤ 0.2
PH（1%water solution）≥ 3.0


Lump Non-ferric aluminium sulphate
Specification: Al2O3:＞17%; Fe:＜0.005%; PH:＞3.0;
Insoluble matter in water:＜0.15%, As:＜0.0005%; Pb:＜0.002%
Granularity: 10-100MM
Use:treatment of drinking water and industrial water, high-grade paper making and high-grade titanium pigment production